Types of Fertilizers
Success Criteria
- Classify fertilizers.
- Discuss the advantages and disadvantages of organic and inorganic fertilizers.
Fertilizers are broadly categorized into two main groups: Organic Fertilizers and Inorganic Fertilizers.
Classification of Fertilizers
1. Organic Fertilizers:
* Farmyard manure
* Compost manure
* Green manure
2. Inorganic Fertilizers:
* CAN (Calcium Ammonium Nitrate)
* DAP (Diammonium Phosphate)
* Compound fertilizers (e.g., Compound A, B, C, D)
* Sulphate of Ammonia
Organic Fertilizers: Exclusive Details
1. Farmyard Manure (FYM):
* Source: A mixture of animal dung, urine, and decomposed plant materials. Urine significantly increases its nitrogen content.
* Storage: Should not be stored in open places to prevent nutrient loss through:
* Volatilization: Nitrogen escaping as gas.
* Leaching: Nutrients washing away with rain.
* Recommendation: Store in a shade.
* Factors Influencing Quality:
* Type of Animal: Chickens and pigs produce higher quality manure due to richer nutrient content in their dung.
* Age of Animal: Generally, older animals produce higher quality manure as their digestion/absorption of food nutrients is less efficient. However, young animals on higher quality feeds can also produce high-quality manure.
* Plant Material (Bedding): Materials that decompose quickly (e.g., grasses, herbs) produce higher quality manure than slow-decomposing materials (e.g., sawdust, maize stalks, wood shavings).
* Period of Decomposition: Kraal manure (animal excreta + bedding) should be fully decomposed before application.
* Advantages of FYM:
* Cost-effective.
* Simple to prepare (no technical knowledge required).
* Improves soil structure.
* Aids in environmental cleanliness by removing waste.
* Utilizes locally available resources.
* Disadvantages of FYM:
* Bulky, making transport difficult.
* Releases nutrients slowly.
* Prone to nutrient loss from poor storage (leaching, erosion, volatilization).
* Can cause fungal infections if applied before complete decomposition.
* May introduce weeds to the field.
2. Green Manure:
* Preparation: Prepared from green plants ploughed into the soil before they flower.
3. Compost Manure:
* Preparation: Made from garbage and other household wastes, heaped and turned to facilitate decomposition.
* Advantages of Compost Manure:
* Does not require livestock for preparation.
* Large quantities can be prepared quickly.
* Utilizes a variety of locally available materials.
* Improves soil structure and aeration.
* Disadvantages of Compost Manure:
* Releases nutrients very slowly.
* Large quantities are required for application.
* Preparation is labor-intensive.
* Can introduce soil-borne diseases and pests.
Inorganic Fertilizers: Exclusive Details
Classification of Inorganic Fertilizers:
Inorganic fertilizers are classified based on:
- Nutrient Composition
- Reaction with the Soil
1. Types According to Nutrient Composition:
* **Straight Fertilizers:** Contain only one essential plant nutrient (Nitrogen, Phosphorus, or Potassium).
* **Examples:**
* Sulphate of Ammonia (21:0:0)
* Ammonium Nitrate (35:0:0)
* Calcium Ammonium Nitrate (26:0:0)
* Urea (46:0:0)
* Single Superphosphate (0:10:0)
* Potassium Sulphate (0:0:40)
* **Compound Fertilizers:** Contain two or three essential fertilizer elements (NPK - Nitrogen, Phosphorus, Potassium). Those containing all three are called complete compound fertilizers (e.g., Compound A, B, C, D). Incomplete compound fertilizers contain two (e.g., 20:20:0, 23:21:0+4s, Diammonium Phosphate (21:52:0)).
2. Types According to Reaction with the Soil:
* **Acidic Fertilizers:** Increase soil acidity or lower soil pH (e.g., Sulphate of Ammonia).
* **Basic Fertilizers:** Reduce soil acidity or raise soil pH.
* **Neutral Fertilizers:** Have no influence on soil pH.
Identification and Properties of Inorganic Fertilizers:
-
STRAIGHT FERTILIZERS:
-
Nitrogenous Fertilizers:
- Properties:
- Readily soluble in water.
- Short residual effects on the soil.
- Can scorch or burn plants on contact.
- Highly volatile (change to gas) when applied to dry soil.
- Highly leached, especially with high rainfall.
- Hygroscopic (absorb moisture from the atmosphere).
- Can corrode skin; avoid handling with bare hands.
- Effects of Excess Application:
- Increased incidence of certain leaf diseases (e.g., rice blast).
- Poor malting in barley.
- Poor combustibility in tobacco.
- Lodging of cereal crops.
- Excessive vegetative growth at the expense of tuber formation in root crops (e.g., Irish potatoes).
- Examples:
- Sulphate of Ammonia (SA), (NH4)2 SO4: 21% N, 26% S. White, crystalline. Highly volatile, acid-inducing.
- Ammonium Nitrate (AN), NH4NO3: 34-35% N (equal ammonium and nitrate forms). White crystalline, highly explosive in refined state.
- Ammonium Sulphate Nitrate (A.S.N), (NH4)SO4 NH4NO3: Mixture of SA and AN. Yellow or orange, granular. 26% N (6.5% nitrate, 19.5% ammonium), 13.5% S. Acidic, hygroscopic, scorching effect.
- Calcium Ammonium Nitrate (CAN), NH4NO3+CaCO3 (Nitro chalk): 21% N (10% ammonium, 11% nitrate). 10-20% quick lime (calcium oxide). Granular, greyish, hygroscopic. Neutral due to calcium.
- Urea, CO(NH2)2: Most concentrated N fertilizer (45-48% N, all ammonium). Granular, white, slightly acidic, extremely water soluble. Highly hygroscopic, volatilizes quickly. Applied as foliar feed (e.g., pineapple) and in livestock feed processing.
- Note: Only a portion of applied nitrogen is absorbed by plants.
- Properties:
-
Phosphate Fertilizers:
- Properties:
- Much of the naturally occurring phosphate in soil is unavailable to plants.
- Form insoluble compounds with other soil minerals.
- Not readily leached.
- Slightly soluble in water.
- In acidic soils, much is converted to insoluble (fixed) compounds.
- Long residual effect (can last up to 4 years).
- Slight scorching effect, unlike nitrogenous/potassic fertilizers.
- Examples:
- Single Super Phosphate (S.S.P), Ca(H2PO4)2 CaSO4: 18-21% P2O5. Contains sulfur (distinguishes from double/triple). Granular, creamy-white (whiter due to high lime content). Releases P2O5 as calcium phosphate slowly. Neutral.
- Double and Triple Super Phosphate (D.S.P or T.S.P): Granular, grey. Contains ~40-49% P2O5.
- Soda Phosphate: Up to 20% P2O5. Contains other elements (30% CaO, 30% FeO, small amounts of Mg, Cu, Zn, Co, Mo, B). Good for soils lacking trace elements. Grey, powdery.
- Basic Slag: 15-16% P2O5, 40-50% lime. Suitable for heavily acidic soils (e.g., clay). Contains trace S, Mn, Mg, Fe, Co, Cu, Mo. Highly basic; should not be mixed with other fertilizers. Grey, powdery.
- Note: DAP and Urea are considered “high analysis” fertilizers due to their high content of essential nutrients (phosphorus and nitrogen, respectively).
- Properties:
-
General Advantages and Disadvantages
Organic Fertilizers:
* Advantages:
* Supplies a wide range of plant nutrients.
* Improves soil structure.
* Helps maintain soil pH.
* Long-lasting influence in the soil.
* Disadvantages:
* Low nutrient values.
* Difficult to determine precise application quantities.
* Bulky, making transport and large-scale application difficult.
* Slow release of plant nutrients.
Inorganic Fertilizers:
* Advantages:
* Supplies required nutrients in precise quantities.
* Easy to transport.
* Easy to apply on large farms.
* Provides instant results upon application.
* Disadvantages:
* Expensive.
* Complex to manufacture.
* Can make soil acidic if acid-forming fertilizers are applied.